Academic Publication Out-of-plane coordination of iridium single atoms with organic molecules and cobalt–iron hydroxides to boost oxygen evolution reaction
Research Abstract & Technology Focus
Advancements in single-atom-based catalysts are crucial for enhancing oxygen evolution reaction (OER) performance while reducing precious metal usage. A comprehensive understanding of underlying mechanisms will expedite this progress further. Here we report Ir single atoms coordinated out-of-plane with dimethylimidazole (MI) on CoFe hydroxide (Ir1/(Co,Fe)-OH/MI). This Ir1/(Co,Fe)-OH/MI catalyst, which was prepared using a simple immersion method, delivers ultralow overpotentials of 179 mV at a current density of 10 mA cm−2 and 257 mV at 600 mA cm−2 as well as an ultra-small Tafel slope of 24 mV dec−1. Furthermore, Ir1/(Co,Fe)-OH/MI has a total mass activity exceeding that of commercial IrO2 by a factor of 58.4. Ab initio simulations indicate that the coordination of MI leads to electron redistribution around the Ir sites. This causes a positive shift in the d-band centre at adjacent Ir and Co sites, facilitating an optimal energy pathway for OER.
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Out-of-plane coordination of iridium single atoms with organic molecules and cobalt–iron hydroxides to boost oxygen evolution reaction
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What is the core focus of the research titled 'Out-of-plane coordination of iridium single atoms with organic molecules and cobalt–iron hydroxides to boost oxygen evolution reaction'?
This literature focuses on: Abstract Advancements in single-atom-based catalysts are crucial for enhancing oxygen evolution reaction (OER) performance while reducing precious metal usage. A comprehensive understanding of underlying mechanisms will expedite this pro...
Are there open-source GitHub repositories related to Out-of-plane coordination of iridium single atoms with organic molecules and cobalt–iron hydroxides to boost oxygen evolution reaction?
Yes, open-source projects like Leonxlnx/agentic-ai-prompt-research (Research into how agentic AI coding assistants work — reconstructed prompt patterns, agent coordination, and security classification) are actively building upon these concepts.
What other academic literature is closely related to 'Out-of-plane coordination of iridium single atoms with organic molecules and cobalt–iron hydroxides to boost oxygen evolution reaction'?
Yes, highly correlated activity was mapped. An entry titled 'Out-of-plane coordination of iridium single atoms with organic molecules and cobalt–iron hydroxides to boost oxygen evolution reaction' discusses this: Abstract Advancements in single-atom-based catalysts are crucial for enhancing oxygen evolution reaction (OER) performance while reducing...
Are there commercial applications of 'Out-of-plane coordination of iridium single atoms with organic molecules and cobalt–iron hydroxides to boost oxygen evolution reaction' in market news publications?
Yes, highly correlated activity was mapped. An entry titled 'Bulk polarization fields and interfacial electron sink in MXene-modified iodine-doped Bi4Ti3O12 enhance piezocatalytic H2O2 generation' discusses this: Efforts to generate H2O2 through mechanical activation are hampered by poor charge control and low efficiency. Herein, a tailored catalyst strength...
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